Breaking that down: Voyager itself couldn't have reduced velocity, it had nowhere near enough reaction mass to do that. Hypothetically a spacecraft could but you might be talking about orders of magnitude more reaction mass. (Which means multiples more of the fuel to launch and accelerate that mass itself, which could quickly escalate beyond any chemical rocket capabilities.)
It also likely wasn't possible to get to Pluto on some future Pluto orbital pass. The limiting factor is likely that Voyager's incoming trajectory to Neptune was already too far beyond solar escape velocity to get into that narrow elliptical orbit you propose. (You'd have to slingshot so close to Neptune's center that you'd hit the planet instead.)
Designing from the beginning to come in slower to Neptune and adjust to encounter Pluto on some future Pluto orbital pass was probably possible, but yeah you might be talking about time scales of Pluto's entire orbit or even multiples of that. (We do similar things for inner solar system missions, like several encounters with Venus separated by multiple Venus-years, but that's on the order of single-digit years and not hundreds.)
The common answer to a lot of these outlandish slingshot questions is usually, yes it's eventually possible by orbital mechanics, but it gets so complicated and lengthy that you may as well just build another separate spacecraft instead. We talk about Voyager's grand tour alignment because it's captivating, but realistically if that hadn't happened we would have just done separate Jupiter-Uranus and Jupiter-Neptune missions instead.
The sun's motion relative to the galaxy doesn't matter for any of this - nothing else in the galaxy is remotely close enough to affect anything, the nearest star is still over 1000x Voyager's distance.