One of the best interviews I've ever heard was Gregory Galant interviewing Fabrice Grinda on Venture Voice in 2009[1].

Grinda is candid and his story is amazing.

EDIT: the awesome interview was in 2005[2], not 2009, although the 2009 one is great too.

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[1] - http://www.venturevoice.com/2009/04/fabrice_grinda_olx.html

[2] - http://www.venturevoice.com/2005/12/vv_show_21_fabrice_grind...