They do sometimes seem surprised that you are using the "offical" words so I gather knowing this is pretty uncommon.
<nostalgia time>I learned it from The Pocket Ref book as a kid</nostalgia time>
I always thought it was a shibboleth, like the tech support reaction I'm sure people here get occasionally where you can hear them realize they aren't going to have to explain how to click on a menu entry to you and switch scripts after you correctly use a technical phrase. Come to think of it, maybe they assume I was/am in the military. That never occurred to me before.
CMU Sphinx and Julius both also have options for continuous speech recognition, but it's quite a feat to train your own [good] language model.
For flying, and for ham radio, we use NATO.
English > NATO may not be easy without memorization, but there's no need to memorize anything if you want NATO > English.