Am considering Ruby at the moment. But reminded of Twitter dropping Ruby due to certain reliability issues. Hence having second thoughts. Or am I a little ahead of myself here worrying about something that may never affect me?
I am no Ruby-ist but I am sure Ruby is not that bad that you will have troubles scaling. You just have to understand how to scale and you can use either PHP or Ruby to apply the general concepts of scalability.
Example: see what they have to offer as open source. Still quite a bit of Ruby: http://twitter.github.com