Don't go to a larger package to get more capacitance, though. Capacitors that are physically larger will have worse higher frequency performance. The physical package is part of the limiting factor. Very high speed designs will prefer 0201 capacitors.
Also keep in mind the distribution of your decoupling capacitors. Putting a single 2.2uF in a board in place of multiple 100nF caps distributed around the PCB would be a mistake. The decoupling capacitor needs to be physically close to what you're trying to decouple.
For hobby projects and microcontrollers most of this just doesn't matter. Pick a capacitor and put it on the board. For real high speed work you have to consider the layout. Number, size, and location of vias around the capacitor has a big impact. Loop area is also a big factor. Don't use narrow traces or locate capacitors far away.