- Carrington event
- Krakatoa eruption of 1883
- large or prolonged earthquake in the New Madrid seismic zone
- the big one around San Francisco
- non-apocalyptic meteor impact (can’t think of a good example)
- there have been reasonably significant variations in climate in the last 5k years or so, and somewhat significant changes on the scale of centuries but I’m not counting them as they’re too slow. The current anthropogenic climate change is faster but I also want to exclude it (and catastrophes in the technical sense like changes to large-scale air/ocean currents, ocean acidification, etc) from the list.