Open floor plan offices. (Sigh.)
Datacenters or server rooms. This could give quite nice data rates within a rack.
The cost of datacenters is not currently constrained by fiber.
There is wifi in datacenters -- usually for the benefit of visiting techs. Not for inside a rack.
Incidentally, if asked to set up 20 workstations on an overgrown table, and it's not a very temporary thing while the office is in turmoil, I recommend finding a different employer.
https://archive.org/details/computernetworks02tane/page/56/m...
Better network speeds in a room surrounded by Faraday cages with MR scanners in them.
Optical is an option but a right pita to run without holing the cage or circumnavigating it.
But for offices, schools, conference halls, and other place with many people together it could be useful as a very fast zero-wire solution. Even then it'll be niche: most office workers or conference attendees don't need 100Mbit let alone more than 1Gbit. But some will: maybe said office is full of video editors and such.
Remember that the bandwidth is a shared resource like WiFi: that isn't "up to 224Gbit/s for every device in the room" it is "up to 224Gbit/s for every device in total". And that "up to" value is for ideal circumstances: there will be some environmental interference (though LOS limitations will work in this techs favour there) and, more significantly, the more devices you have in a given collision domain the more they will interfere slightly with each other too because they can't share the group resource with complete efficiency (and this difficulty grows exponentially after a certain threshold). Get a couple of machines transferring arbitrary data as far as they can via WiFi, take the total of transfer speeds they are getting and now add more machines doing the same. The total might scale well for an irritation or two of this test, but there will be a pint when it significantly won't and the total bandwidth will actually fall (and latency will shoot up).
The main push for 5G mobile networks wasn't better max bandwidth per device, but better performance (latency and throughout) for every device when you have a lot of them sharing the same collision domain. The headline figure of 224G bit is (while not at all dishonest) just that: a figure to gain interest via headlines. Those who actually have a need or want for such tech will be looking much deeper into it than that.
I can only think of useful for conference where everywhere there's light.