I like the idea. I am surprised by the negative comments. Getting a professional headshot is both time-consuming and expensive, so if this service works as promised it definitely will be useful, and I would be willing to pay for it. So why haven't I already signed up? A few things made me nervous:
1. The "contact us" link is broken, which doesn't inspire confidence.
2. It's important to me that you don't leak or retain my data, and while I know you say you don't retain it, I will just have to take that on faith and I'm not sure I'm willing to do that.
3. Your examples include novelty shots like "pharaoh" and "superman" etc. This branding is confusing. If you're targeting people who want professional shots for their LinkedIn etc then why would you offer jokey picture styles?
If you can solve these issues then you can count me in as a customer.