No, in many cases it's a much slower agonizing death. But you might get a gold watch at the end!
I've seen startled cattle, and I've seen frightened cattle. None of these were. Yet inside, the sound of dying cattle could be heard, with a "Bam!" from the gun used to euthanize by nail-to-the-brain, and a "thud' of the cattle falling afterwards.
I presumed, at the time, that the lack of concern was due to a lack of panicked sounds. The cattle simply died instantly, without exhibiting any pain response, or noise, first.
So no.. at least for cattle, it seems to be without the experience you describe.