It's a very useful skill, and worth learning if you're going outdoors. But it's not as simple as looking at road maps and reading street signs.
Coincidentally, there is a great Sierra Club program in Los Angeles & Orange County that teaches off-trail navigation (among other skills)... It's called the Wilderness Travel Course, and it's great fun. I believe the Mountaineers in the PNW also teach those skills as part of their leadership program.