I think it's an organisational problem rather a technical one to be fair.
You can (could) fly Perth to London. But will Perth put up with extra flights when (say) Singapore won't? And Western Australia has closed it's borders too, so you'll need political approval, can you get that? And are you sure you will have aircrew that will do the trip? And 26h is a long time to be on a flight, what happens if someone starts coughing harder and harder, you can't leave them at the midpoint. And remember, your airline is now on the verge of bankruptcy, so there isn't a budget for any of this and everyone senior is busy...
Interestingly they were talking about doing London-Sydney back in Jan. Popular Mechanics had an article about re-enforcing the Hull so pressure inside could be higher so you would not feel as rough at such a long flight...