I always thought 256 vs 200 was a PAL vs NTSC thing? Is that wrong?
I can't speak to why they differ exactly though.
320x200x60 = 384k lines 320x256x50 = 410k lines
Akshually, the horizontal (BW) resolution has little to do with timing. It's as good as the analog components are and as good the computer can output. Amigas had 1280x256 resolution, if you wanted, on standard PAL equipment. (On a fuzzy TV set, you weren't likely to appreciate 1280 horizontal resolution though.)