Targetting 320x256 makes it harder to port to 320x200. Meanwhile, porting 320x200 to 320x256 is easy, just add a small letterbox.
I can't speak to why they differ exactly though.
320x200x60 = 384k lines 320x256x50 = 410k lines
Akshually, the horizontal (BW) resolution has little to do with timing. It's as good as the analog components are and as good the computer can output. Amigas had 1280x256 resolution, if you wanted, on standard PAL equipment. (On a fuzzy TV set, you weren't likely to appreciate 1280 horizontal resolution though.)