That's really interesting to know, actually. I've only been with companies that had MySQL installations (Facebook and Twitter) and so jumping in was really easy, but on the other hand I do like to do things right. A few questions, though:

0/ How would I be able to tell if the limitations of our DB are because of MySQL and would be solved by PostgreSQL? That is, common pain points in MySQL that we wouldn't recognize immediately until we switched? (Edit: mostly looking for performance-related, but anything is fine.)

1/ Is there a PostgreSQL consulting firm that has the same reputation that Percona does with MySQL?

2/ Is there a good place to start when there's an issue or question I have with PostgreSQL (aside from IRC)? With MySQL I've been either going to the docs, or to Google, but it's been spotty with either.