Is it harder to find tutorials for PostgreSQL? Yeah, maybe. Is it harder to get high-quality advice and resources from subject matter experts? No; in fact, it's far easier. I have used PostgreSQL for many years and in all of them every question I've had has been answered quickly and properly by somebody in #postgres who knows way more about postgres and SQL than I'd ever even want to know.
And what about hires? When a million people "know" MySQL it takes a lot more effort to find somebody who actually does. There may be fewer contractors for PostgreSQL but they are practically by definition better than the average MySQL contractor.
unlike learning a programming language, with databases, the domain knowledge is harder to discover and more risky if you don't understand it
Exactly. So should you trust the ecosystem that relies on lazy, bandwagon developers for the majority of its market share, or the one that has been silently doing shit the right way for years? There may be a whole lot of really skilled MySQL admins out there (I guess there must be given how many huge sites go to extreme lengths to make MySQL work for them), but I can find you a handful of grossly overqualified PostgreSQL admins in no time. The same can't be said for the former.