Hardware has, in addition to the GPIO, UART and ADC/DAC that you're used to from Atmel, a USB 2.0 device controller (it says "OTG", which implies a host controller too, but sometimes people get this mixed up), a SD/MMC/eMMC controller for storage (no idea about SDIO) and gigabit ethernet.
I'm a little disappointed in the lack of wireless connectivity on the SoC, though I suppose you can make up for that with off the shelf USB devices (or a UART bluetooth radio).