I am surprised by this, as I have had the opposite experience.
I moved from a windows to mac a few years back, adopted alot of the keyboard shortcuts and recently a few months ago back to windows primarily. I found that on a mac the same shortcuts I use in the terminal (readline bindings), I can use most everywhere (ctrl-a for line start/ ctrl-w to kill last word etc...). For the most part Vimium takes care of the browser.
I have often found the windows shortcuts to be hidden an obscure. Alt+F4 is the defacto kill app on windows but trying to press it is inconvenient especially while Alt+tabbing through windows.
I agree command and control can be confusing but they give you more range in keyboard shortcuts as a result. The windows 8 search (although an improvement over 7) is also medicore compared to OSX spotlight making it much easier to CMD+Tab and navigate to different apps.
The least keyboard friendly part is certainly the windows cmd prompt where pasting is ALT+SPACE+E+P ... as opposed to CMD+V on OSX... not mention the lack of navigational shortcuts in the cmd prompt (kill back a word, kill rest of line etc...)
The most frustrating part for me is windows shortcuts not being consistent throughout apps. In most of the windows CTRL+BACKSPACE will kill the last word but not in notepad? or most winform applications... Ctrl-F is find in most apps but "forward email" in outlook?
I guess its really a matter of personal preference, but I think as far as keyboard shortcuts go, both OS's have plenty.