A standardized HEPA filter removes 99.97% of particles down to PM0.3. How much it cleans the air in the room in the end depends on many factors, but in a small room and a decent filter you can expect a significant reduction in pollution.
So yes, if you want less pollution, a HEPA filter will deliver it in a theoretical range of zero to 99.97% purification, depending on the variable factors of room size, air circulation, purifier air flow and so forth.
A properly sized purifier will circulate all air in a room several times per hour, so in practice you can expect a good cleanup of particulates (perhaps around 80%) in a fairly short period of time (less than an hour).