The sleight-of-hand comes in around 14:30 into the video, where we are told to create the sequence for an "uncountably infinite number of starting points." That's exactly the point where the construction is non-constructive, and the infamous Axiom of Choice is used. There is no construction - in the sense of constructive mathematics - that can achieve what is described at this point.
Banach-Tarski is not generally regarded as some deep fact about mathematics, a point the video mistakenly belabors. Rather, it is a consequence about particular axiomatizations of set theory which admit the Axiom of Choice. Banach-Tarski is only valid with the Axiom of Choice, and in fact that is the main interest in the paradox.
In my personal opinion, the Banach-Tarski paradox isn't much more enlightening than the simpler construction of the Vitali set (assuming the Axiom of Choice), which is a non-measurable set of real numbers (with Lebesgue measure, i.e., length).
Another part of the video I find misleading has to do with the hyper-dictionary, where he describes the hyper-dictionary by putting some parts of the dictionary "after" other parts which are infinitely long.
The putative applications of Banach-Tarski to physics are ridiculous. Uncountable sets are fundamentally unphysical. The Axiom of Choice serves mainly as a convenience to mathematicians when either a proof avoiding the Axiom of Choice would be more complicated, or so that mathematicians can state properties of objects which are set-theoretically larger than anything that can be relevant to physics anyways.