I recently started taking L-Theanine and caffeine (mostly via coffee, but I occasionally use caffeine powder). It seems to give me some solid focus for a few hours, but to be honest I'm not sure if it's a placebo effect.
I still have the majority of a bottle left, so maybe I'll skip the caffeine and give it another go at some point.
Keeps me alert and awake in the morning, which is when I tend to have the least motivation.