Options that are not liquid, however are a different kettle of fish. Mentally, I will usually value them at close to zero when comparing with other job offers (because more often then not that's what they'll end up being worth).
Outside the valley nobody cares about stock options. Even within the valley many people are aware they're a gamble at best. You're most likely not working for the next Facebook.
1) Very few candidates would leave a well paying job where they are constantly learning for a bit more money. I wouldn't leave my current company for less than a 20% raise.
2) A well trained productive employee is worth much more than market rate. However, due to information asymmetries the market is rarely going to pay them even 20% more than average.
Combine 1 and 2 and you see that all a company has to do is offer 20% over market rates and offer in depth training etc and they will have great retention.