I don't understand why so many businesses use a product with such a weak SLA as their main mode of communication. Both Hipchat and Slack have terrible uptime guarantees, and you should stay away from them.
Everyone will always be reachable with effort, even in a group setting. Slack isn't an infrastructure critical component (such as Github or AWS) where 0.001% downtime would effect my business. Slack's utility far outweighs the prospect of a few hours (max) of downtime a month.