* I seem to install Json.net in every .NET project I create (json serializer - thanks James Newton-King!)
* NLog for logging. It's fantastic.
* Dapper is also excellent (Micro ORM) (and anything written by Marc Gravell is generally top-notch - see protobuf-net, miniprofiler, StackExchange.Redis)
* Automapper, to avoid writing boilerplate code to convert between similarly shaped types (E.G. DTOs to DB models).
* RestSharp makes talking to RESTful apis easier.
* Microsoft's Unity is a great IOC framework, although most people seem to use NInject.