From a natural language standpoint, I have found J [1] particularly interesting. Kenneth "not Alan" Iverson [2] extended and refined the the ideas he developed for APL [3] and mapped it onto the ASCII character set. Like APL, J is built on a grammar of nouns, verbs, adverbs, etc. with the idea that the labels for the language's parts map reasonably to their counterparts in natural language (for some definition of "reasonably").
One of the great things about J is it's documentation. Originally a commercial product, J's documentation includes great tutorials and primers that someone was paid to write (as opposed to produced instead of doing the coding they love).
[1]: http://www.jsoftware.com/
[2]: https://en.wikipedia.org/wiki/Kenneth_E._Iverson
[3]: https://en.wikipedia.org/wiki/APL_%28programming_language%29