RSUs tend to be better because, unless your company goes out of business, they're usually at least worth _something_ when they finally vest. One thing about stock, however, is that after they're all vested, you're effectively seeing a decrease in your overall compensation. An RSU package that fully vests after 4 years incentivizes you to start looking for a new job after 4 years.
When I get an offer that contains options, I usually mentally value it at $0 and THEN consider whether the salary still seems competitive.
EDIT: I generally value _options_ at zero.
I also LOVE kasey_junk's strategy below of asking companies what they'd hypothetically offer in cash instead of equity. That's pretty much guaranteed to make the company get real about how they value their equity. I remember once negotiating ~$5K more in base salary to "give up" what OMG COULD TURN INTO MILLIONS OF DOLLARS IN OPTIONS!!!! The company eventually went bust and sold for pennies on the dollar.