I originally started Bolt to learn about the implementation details of low-level data stores. It started as a pet project but became more serious as I filled it out and added additional layers of testing.

I'd honestly suggest reading through the source code of some database projects. That's the best way to learn the structures and understand the engineering tradeoffs. Some are more approachable than others though. Bolt and LMDB are 2KLOC and 8KLOC, respectively. LevelDB is 20KLOC and RocksDB is 100KLOC, IIRC.

If you want to go further then I'd suggest porting one of those over to a language you know well. It doesn't have to be code you release to the world or use in production but just porting the code really helps to cement the concepts in my head.