http://i.imgur.com/44lkXHa.png
Edit: Clearly it's not the only reason they've succeeded, they've smartly avoided all the capital infrastructure that Webvan relied on and mobile devices have improved tremendously but when you're talking about tenths of a percentage points in penetration, tripling your TAM is huge.
Amazon Fresh is doing this with their own warehouses and robots. They know their own inventory, and will probably crush these manual-picking operations.
It's a race to see who can take the market, and Amazon is taking a slower, infrastructure based approach. It will be interesting to see if they will see it through to the end.
Webvan had a ton of CapEx spending on infrastructure.
I don't think Instacart has to worry about B&M warehouses or fleets of delivery trucks.