I'd be more interested, why you moved from Mongo to Postgres.
Take a look at postgres hstore with a gin index.
Now, with the jsonb support coming in 9.4, PG gets pretty much everything I once liked Mongo for.
http://www.postgresql.org/message-id/E1WRpmB-0002et-MT@gemul...
http://thebuild.com/presentations/pg-as-nosql-pgday-fosdem-2...
Furthermore, consider that PG is pretty much an amazing RDBMS in addition to having a good document story.