I've worked on enterprise products, off-the-shelf and in-house, which use message brokers, and every time I could not fathom how the extra complexity was justified. If the messages were just queued in a simple database table instead, the implementations would have been much easier to work with: easier setup and admin (it's just part of the existing database), easier to check and monitor (just select counts from the table), easier to inspect the pending messages and fix problematic messages. In all cases I get the feeling the architects were just looking for an excuse to use a new technology.
I can only see high-load scenarios as a possible justification, where the volume of incoming message data is physically too much for the RDMS.