What part of that sequence of events were you unable to do before KeyMe or KeysDuplicated?
A store clerk might be telling me to wait a bit for the key to duplicate, but in reality call the cops on me; there are cameras in hardware shops which can identify me and the bundle of keys and also there are other customers in the store.
So, I don't think these services really change the game at all, but perhaps provide a new level of information to the general public?
Hopefully, as a rule, people would tend toward protecting their keys. Here's a gorgeous Cartier key protector: http://www.liveauctioneers.com/item/25421384_a-cartier-of-lo... if you want to do it style.