Our new DC are all IPv6 enabled (we started launching them in December) with dual stack, and preference for IPv6. Only 1 of the DCs are online so far, and we're already pushing around something like 3 Gb/s of traffic over V6. It was nice how many things just magically worked atop V6, once we added AAAA records.
One thing that was sad though, is how poorly everything built atop, and around Ruby worked.