The main reason that copper is so valuable is it has so many uses and is very easily recycled(I saw an estimate that said 80% of all the copper ever mined is still in use) so holds it's value (You often get 90-95% of its commodity value for recycling).
Copper is always in demand, has a bajillion uses, and can be scrapped and reworked very easily. This is why you hear about meth heads stripping copper wiring out of old homes. It's not that the copper is incredibly precious. It's that the copper is so easily liquefied into cash at any number of one-stop, no-questions-asked destinations.
Copper is expensive as a building or product material, not in and of itself, but in relation to many of the alternatives in any given application. Small differences in component costs, scaled over large supply chains, add up to huge differences in margin at the macro level.
On the other hand there are not that many uses for pure copper (most of them are electricity related) as there are many other metals or copper alloys that are significantly cheaper.
http://www.onlinemetals.com/merchant.cfm?id=1288&step=2&top_...