Don't want to argue, but yes it would. It would stop the user for a second, giving time to the brain to process for a while what's going on.
I think anyone who would blindly use your proprietary two factor solution that makes it easier for end users to authorize other people to log in would be silly.
'No 2FA' is the real silly one here. Any 2FA is so much better than no 2FA, and usability has been a big issue so far in 2FA adoption.