In late 2009, the most visible seller was NewLibertyStandard[1], who had a unique pricing methodology[2].
You could buy roughly a thousand bitcoins for $1. This was widely considered overcharging.
[1]: http://newlibertystandard.wetpaint.com/page/2009+Exchange+Ra...
[2]: "During 2009 my exchange rate was calculated by dividing $1.00 by the average amount of electricity required to run a computer with high CPU for a year, 1331.5 kWh, multiplied by the the average residential cost of electricity in the United States for the previous year, $0.1136, divided by 12 months divided by the number of bitcoins generated by my computer over the past 30 days."
There weren't even 1.3 million bitcoin in circulation at that point [1]. If you bought every bitcoin, you could have accumulated about 1.1 million BTC for $850.
[1] http://blockchain.info/charts/total-bitcoins?timespan=all&sh...
However, if someone had bought coints for even 100usd back in 2010 that would have been weird too and affected the network perhaps a little too negatively.
Indeed, 1.3 million is over 10% of all bitcoins available at the moment.
But there is no doubt that buying that many bitcoins at that time would have been difficult. The few sellers you would have been able to find would have probably raised their price when seeing your interest.
[1] http://www.theguardian.com/technology/2013/oct/29/bitcoin-fo...
[1] http://bitcoinity.org/markets/list?currency=ALL&span=30d
Satoshi implored people in December 2009 (several months after this post) to postpone mining using GPUs for as long as possible[1].
I commented on it here: https://bitcointalk.org/index.php?topic=40876.msg520645#msg5...