It doesn't actually unlock your machine. If you lock your computer it will not work. What it does is put up a page that looks nearly identical to the login page with small changes. It's a cool app (I tried it) but I'm disappointed that I can't find a way to toggle the lock via Alfred/Keyboard shortcut.
I can get in the habit of hitting a key combination/alfred command when I get up but having to click the icon in the menu bar will get annoying.