Thanks for the interesting information. I'm skeptical that the Z-80 designers were planning ahead for 16 bits, though. Simpler BCD math is a possibility - I'll look into this as I examine the Z-80 more. The 6502 wins, though, for crazy but efficient decimal arithmetic - it has a complex patented circuit that detects decimal carry in parallel with the addition/subtraction, and another circuit to add the correction factor to the result without going through the ALU again. So you don't need a separate DAA instruction or additional cycles for decimal correction.
General question: what things about the Z-80 would you guys like me to write about? Any particular features of the chip? Register-level architecture, gates, or the silicon? Analyzing instructions do cycle by cycle? Gate counts by category? Comparison with other microprocessors?