We ditched PgPool for PgBouncer for connection pooling from our webservers. PgPool tries to do way to much, and the documentation is horrible. PGBouncer been rock solid compared to PgPool.
I'd love for PgBouncer to poll the servers it's connected to and automatically talk to the master, so in case of master failure I would only have to promote a new master (and STONITH) and PgBouncer would auto-failover to the new master.