The front page should not have a page number.
Please place a header on each page. On the even pages, the header should be on the left, on the odd pages, the header should be on the right. On the bottom-center of each page, place the page number, except for the front page, as specified above.
The above is probably a bit much, but it is, as far as I know, absolutely impossible to do in Libre Office, or it is not, it is extremely difficult to do, but this sort of formatting is absolutely trivial in MS.
If the above sounds to complex, then try creating a working TOC in Libre Office.
The grammar and spell-checking capabilities are not very good in LO.
I've also had many doc -> PDF conversion problems in LO. There are many other smallish issues.
LO is about as much of a replacement for MS Suite as Gimp is a viable replacement for Photoshop for productivity and real-world work. I use the FOSS stuff at home, but my overall productivity is way lower at home as well. I've ran into many things I simply cannot do. It really is a cost-to-productivity ratio here. MS Suite really isn't that expensive if you compare the speed and accuracy you can accomplish common tasks.