What do you mean $75k in avail credit? I'm just curious. Do you mean you used the online/phone based "spending check" to see if they would approve a $75k charge? Except in cases of borderline credit Amex doesn't publish spending guidelines on charge cards. Unless you meant a revolving product, but usually when somebody says Platinum they mean the Amex Platinum charge card.
Also, there's some serious caveats and differences here. If it IS a charge card, you'll have to pay it off within 60 days. If you don't, you'll definitely see some adverse action from Amex not to mention a HIGH apr. Even if it is a revolving card like the Amex Skymiles Plat or the MB Plat, if you start revolving a 5-figure balance Amex will most likely investigate and you could get investigated (a request for your 1040's) and/or see some adverse action.
Finally, Amex has a lot more sophisticated risk models than other lenders, because they have to. I can charge as much on my Amex PR Gold card as all of my other credit limits combined -- just about $100k. They aren't as Fico reliant.
Have you seen your Fico scores recently? (There are about a dozen different true Fico scores, and endless knockoffs that are useless). If you've seen your Fico from something like MyFico.com and it's over 700 you could still have a problem with the Auto Enhanced Fico product that many lenders use for auto loans. That scoring model emphasizes installment loan history which it seems is your sore spot.
If I were you I'd head over to CreditBoards.com and learn how to clean up the negative info on your reports and get your auto loan problem fixed up.