So, I'm going to wager this vulnerability affects about 99.99% of the users.
People who used both Skype and MSN (Live Messenger) were shifted from MSN to Skype and now use their Microsoft account to connect to both lists of contacts in Skype. So it's not just for the geeky few who have set this up.
Second thought: last I checked, I could log-in to Skype with both my old username and my Microsoft account, but my Skype username didn't allow me to view MSN contacts. So if that's still the case, then I guess this would affect 100% of people, even those who have made the switch.
Actually, a while ago, while logging into Skype, I got a clear invitation to switch to a Microsoft account.
I ignored it at the time, but I'm reconsidering in light of the mentioned attack.
Edit: There doesn't seem to be any switching possible; you can only merge a Microsoft account with a Skype account.
http://about.skype.com/press/2011/05/microsoft_to_acquire_sk...