a. The OS felt as responsive as Windows Phone and all the custom gesture recognition works as advertised(e.g. Peek).
b. The apps I used included Twitter, the Blackberry Hub (e-mail, contact etc.), the Camera app and Evernote. Of these, the Evernote app seemed to be a little rough (mainly UI glitches), but the rest worked well.
I haven't used the Developer Toolchain for QNX/BB10, but have friends who seem to think that it's not too bad. They are waiting for sales figures to decide whether or not they should think about releasing a BB10 app.
Off-topic: As someone who likes tinkering with things, hardware repair-ability is something I pay attention to. The Z10 is the most repairable phone out there according to iFixit (8/10): http://www.ifixit.com/Teardown/BlackBerry+Z10+Teardown/13445...