Go ahead and make a mini Go app, re-implement half the features that Express in Node has, then benchmark the 2 with real data using the same data and templates.
Come back when you see that once you start pulling records in from mongodb or somewhere else and start rendering either server side templates with this mongo data or serving json back then the performance differences of the 2 frameworks begin to disappear.
Node will perform better under high concurrency too for most sized responses.
So where's the motivation to switch? If I switch to Go then I have to learn Go + I'm still using Javascript on the front end.
If I stick with Node then I can use my JS knowledge on both ends. This is a really big deal for day to day web app programming and is a deal breaker for html5 games.
Go cannot be taken seriously to be used for web apps until it offers actual performance gains over JS and gets something that lets you write Go but it spits out JS for the client, sort of like Java has GWT (ps. that bombermine mmo uses GWT).
There's also a serious lack of good light weight web frameworks for Go. None of them come close to what Express does for Node, and I'm not the only one who thinks Express is really close to an excellent mix of features without getting in your face.