Will you happily pay $20k if you know that someone else, billing by the hour for the same quality of work, will cost you $10k?
If you want to do value based pricing, you need to have a sales pitch that differentiates you from the market, or risk pricing yourself out of said market.
Making a lot of money per <hour|day|week|...> doesn't come down to just asking for it. You have to market yourself.
As others have stated elsewhere in this thread: there are people who are willing to pay you a lot of money so you can free up their time and let them focus on activities that generate a boatload more money than $10K. These are the people who will happily choose the $20K offer, and these are the people you want to work with.