Thing is, for a serial TTL connector to become ubiquitous, it needs to cover at least something like 99% of scenarios. Or maybe 95%. 3.5mm TRS ain't that, and thus just increases general diversity in connectors.
I assume the possibility of spurious Rx state is why FTDI chose to wire Rx to the tip pin of the female TRS connector: It's the last pin to make contact with anything when plugging in, and therefore least likely to be bridged to ground. I suppose the mechanical design of any particular jack would determine whether it's possible at all.