As far as I know there's not actually anything particular to 2.4 GHz allowing higher throughput for LoRa than that the corresponding Semtech chip happens to support wider bandwidths. (I.e. no legal barrier.)
The tradeoff is less range due to lower link budget. Doubly so because 2.4 GHz has higher free-space path loss. You're not going to get outside your house with these speeds. The primary use (as stated in the original post) is likely through clear space with a directed antenna.
(The 2.4 GHz band is better suited to this use since you can use antennas with higher than 6 dBi gain. If my math is correct, anything higher than 11 dBi is a win even accounting for FSPL and the power derating the FCC imposes.)
(Aside, I am the author of that MeshCore ticket.)