> picking up pennies in front of a steamroller.

This or any other statistical play is only 'in front of a steamroller' if you do it with leverage, especially if notionally uncorollated bets suddenly move together. Bets on Polymarket have limited downside by design, and bets in different categories are obviously unrelated to each other.

Without having looked into this in detail, however, I suspect the problem would be limited capacity; markets that are both deep and so trivially irrational are probably fairly infrequent. You might pick up pennies but only pennies.