No. DUP will happily put both copies on the same disk. You would need to use RAID1 (or RAID1c3 for a copy on all disks) if you wanted a guarantee of the metadata being on multiple disks.
...even so, without a disk failure, that probably wasn't the cause of this event.
You can end up in this state with btrfs if you start with a single device (defaults to data=single,metadata=dup), and then add additional devices without changing the data/metadata profiles. Or you can choose this config explicitly.
I really wish the btrfs-progs had a --this-config-is-bad-but-continue-anyway flag since there are so many bad configurations possible (raid5/raid6, raid0/single/dup). The rescue tools are also bad and are about as likely to make the problem worse as fix it.