But that's besides the point. When people say "RDBMS" or "filesystem" they mean the full suite of SQL queries and POSIX semantics-- neither of which you get with KV stores like BigTable or distributed storage like Colossus.
The simplest example of POSIX semantics that are rapidly discarded is the "fast folder move" operation. This is difficult to impossible to achieve when you have keys representing the full path of the file, and is generally easier to implement with hierarchical directory entries. However, many applications are absolutely fine with the semantics of "write entire file, read file, delete file", which enables huge simplifications and optimizations!