Aluminum has a higher resistance, which means the same diameter will get hotter than copper. Make the cable thicker and its resistance drops, which means it gets less hot.
Want more amps at the same temperature? Ohm's law still applies: just use a thicker cable.
Wire can be used for up to whatever ampacity is listed for that size wire and temperature rating in Table 310.16 (Conductor Ampacity) Copper and aluminum have separate ampacity tables because you need to use larger aluminum conductors.
Example:
#250MCM THHN copper can handle 255A in a commercial setting (75C column)
#250MCM THHN aluminum can handle 205A in a commercial setting (75C column).
NEC ampacity table: https://media.distributordatasolutions.com/ThomasAndBetts/v2...