Well, not exactly. This is actually a great example of the Go philosophy of being "simple" while not being "easy".
A Vec<T> has identity; the memory underlying a Go slice does not. When you call append(), a new slice is returned that may or may not share memory with the old slice. There's also no way to shrink the memory underlying a slice. So slices actually very much do not work like Vec<T>. It's a common newbie mistake to think they do work like that, and write "append(s, ...)" instead of "s = append(s, ...)". It might even randomly work a lot of the time.
Go programmer attitude is "do what I said, and trust that I read the library docs before I said it". Rust programmer attitude is "check that I did what I said I would do, and that what I said aligns with how that library said it should be used".
So (generalizing) Go won't implement a feature that makes mistakes harder, if it makes the language more complicated; Rust will make the language more complicated to eliminate more mistakes.